Rhodium-mediated Carbene Insertion: Synthesis of (-)-hamigeran B and the (-)-sordaricin Core

Rhodium-mediated Carbene Insertion: Synthesis of (-)-hamigeran B and the (-)-sordaricin Core

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The work presented here is divided into four projects, each with a specific aim. All but the last project derive from alpha-aryl ketones, and all of the projects share the common theme of extending the practical use of carbenes/nitrenes in organic synthesis.... 803; LRMS (CI) m/z (rel. intensity) 312 (1), 310 (1), 171 (20), 169 (20), 141 (100 ), 90 (14); HRMS calcd for C 16H25N79Br (M+H) 311.1011, obsd 311.1008. Ketone 4e: The ketone 4e was prepared following the same procedure as synthesisanbsp;...


Title:Rhodium-mediated Carbene Insertion: Synthesis of (-)-hamigeran B and the (-)-sordaricin Core
Author:
Publisher:ProQuest - 2008
ISBN-13:

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